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By simultaneously targeting glucose transporter type 1 (GLUT1), a glucose transporter critical for glucose uptake, and glutathione synthesis, which is intimately linked to NADPH production and reactive oxygen species scavenging, it may be possible to deplete NADPH levels and cause a buildup of reactive oxygen species

Flores-Mndez M, Mendez-Flores OG, Ortega A (2016) Glia plasma membrane transporters: key players in glutamatergic neurotransmission

Because they ensure that cellular functions like metabolism and mitosis are running smoothly, a deficiency in any of B vitamins can lead to fatigue, weakness, and yep, you guessed it headaches