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References National Institutes of Health World Health Organization MedlinePlus National Center for Complementary and Integrative Health This article is for general information only and is not a substitute for professional medical advice
[20] [7] This conversion is illustrated by the reduction of peroxides (via the sulfenate as an intermediate): GSH + R 2 O 2 GSOR + ROH GSOR + GSH GSSG + ROH Net reaction: 2 GSH + R 2 O 2 GSSG + 2 ROH (R = H, alkyl) and with free radicals, forming glutathionyl radicals (GS ) that may dimerize to disulfide: GSH + R RH + GS 1/2 GSSG Thiyl radicals (such as glutathionyl radicals) are themselves oxidizing species in biology, with a single-electron reduction potential sufficient for oxidation of nucleic acids, proteins and polyunsaturated lipids
doi:10.1073/pnas.1216100110 10
Under physiological conditions, laminar blood flow keeps the vascular wall in a quiescent state, with a predominance of NO signaling, which inhibits inflammation, cellular proliferation, and thrombosis [55, 56]
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